YAMADA Group
Laboratory of Organic Chemistry,
Department of Chemistry, Tokyo Gakugei University
東京学芸大学教育学部 自然科学系基礎自然科学講座
Reseach Overview
Our research centers on the molecular design, synthesis, and functional exploration of π-conjugated molecular systems, with a particular emphasis on fullerenes and nanocarbon-derived architectures. π-Conjugated frameworks exhibit distinctive electronic properties arising from unique topology, enabling emergent electronic and photophysical behaviors beyond those of conventional organic molecules.
A major focus is the presice structural manipulation of fullerene cages, achieved through the development of cascade reaction systems and tether-directed regioselective transformations. These approached provide access to unconventional nanocarbon scaffolds that cannot be obtained by conventional chemical reactions.
In parallel, we investigate the noncovalent interactions on fullerene surfaces, which govern the macroscopic properties and functions. To quantitatively explore these subtle interactions, we employ a molecular torsion balance system and systematically evaluate the effects of polarity, dipole moment, polarizability, and charge on intermolecular forces.
By integrating synthetic chemistry, spectroscopy, computational chemistry, and materials evaluation, we aim to reveal the governing principles underlying structure—property relationships in π-conjugated nanocarbon systems. The resulting knowledge provides a foundation for next-generation applications, including organic photovoltaics, molecular recognition, inhibitors, and supramolecular assemblies. Ultimately, our goal is to establish a new paradigm for molecularly programmable nanocarbon materials, in which structure, reactivity, and function are designed in harmony at the atomic scale.